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Fluorides

Hydrogen fluoride (01006)

Anhydrous, 100%

Overview
AHF is used to produce environmentally preferred fluorocarbon products, fluoropolymers, and chemical derivatives. It is a clear, colorless, corrosive fuming liquid with a sharp, pungent odor. AHF is 100% soluble in water and is not flammable. It forms a dense white vapor clouds if released. AHF is highly hazardous and needs to be handled and used with rigorous safety precautions. It can cause severe burns to all parts of the body in liquid and vapor forms. Specialized medical treatment is required for all exposures to HF acid.
Specifications

General Information

  • Application
    • Blowing Agents
    • Petrochemical
    • Plastics
    • Refrigerants
    • Solvents
  • CAS Number
    • Hydrogen Fluoride - 7664-39-3
  • Concentration
    • 100% Hydrogen Fluoride
  • EC Number
    • 231-634-8
  • Grade
    • Anhydrous
  • Performance Function
    • Fluorinated Carbon Compounds
  • Product Type
    • Substance Degrees Celsius
  • Synonyms
    • AHF
    • Anhydrous HF
    • HF
    • HF Acid

Physical Properties

  • Boiling Point/Range
    • 19.5 °C at 1.013 hPa
  • Chemical Composition
    • Hydrogen Fluoride
  • Color
    • Colorless
  • Density
    • 1,000 g/cm3 at 20 °C
  • Flashpoint
    • Not applicable
  • Formula
    • HF
  • Melting Point/Range
    • -83 °C
  • Odor
    • Intolerable Pungent
  • Partition Coefficient
    • No data available
  • pH
    • Acidic
  • Physical Form
    • Liquid
  • Solubility in Water
    • Completely miscible
  • Vapor Pressure
    • 1.028 hPa at 20 °C hectopascal

Safety Information

  • Chemical Stability
    • Fire or intense heat may cause violent rupture of packages
    • Stable under normal conditions
  • Corrosivity
    • Extremely Corrosive
  • Evaporation Rate
    • Not applicable
  • Flammability
    • Not applicable
  • Ignition Temperature
    • Not applicable
  • Incompatible Materials
    • Contact with alkalies and some oxides cause strong violent exothermic reactions
    • Contact with metals will yield hydrogen gas, a fire and explosive reactive hazard
    • Glass and silicate-containing materials are attacked
    • HF contact with carbonates, sulfides and cyanides yield toxic gases such as carbon dioxide, hydrogen sulfide and hydrogen cyanide
    • HF contact with glass, concrete and other silicon bearing materials will yield silicon tetrafluoride gas
    • On dilution or dissolving in water, considerable heating always occurs
    • Pressure buildup from this process has been known to rupture glass containers
    • When diluting, add acids to water, never the other way around
  • Oxidizing
    • The substance or mixture is not classified as oxidizing
  • Self Ignition
    • Not applicable
  • Thermal Decomposition
    • Fire or intense heat may cause violent rupture of packages

International Transportation

  • Chemical Class
    • 8
  • Packing Group
    • I
  • Sub Class 1
    • 6.1
  • UN Number
    • 1052

General Information

  • Application
    • Blowing Agents
    • Petrochemical
    • Plastics
    • Refrigerants
    • Solvents
  • CAS Number
    • Hydrogen Fluoride - 7664-39-3
  • Concentration
    • 100% Hydrogen Fluoride
  • EC Number
    • 231-634-8
  • Grade
    • Anhydrous
  • Performance Function
    • Fluorinated Carbon Compounds
  • Product Type
    • Substance Degrees Celsius
  • Synonyms
    • AHF
    • Anhydrous HF
    • HF
    • HF Acid

Physical Properties

  • Boiling Point/Range
    • 19.5 °C at 1.013 hPa
  • Chemical Composition
    • Hydrogen Fluoride
  • Color
    • Colorless
  • Density
    • 1,000 g/cm3 at 20 °C
  • Flashpoint
    • Not applicable
  • Formula
    • HF
  • Melting Point/Range
    • -83 °C
  • Odor
    • Intolerable Pungent
  • Partition Coefficient
    • No data available
  • pH
    • Acidic
  • Physical Form
    • Liquid
  • Solubility in Water
    • Completely miscible
  • Vapor Pressure
    • 1.028 hPa at 20 °C hectopascal

Safety Information

  • Chemical Stability
    • Fire or intense heat may cause violent rupture of packages
    • Stable under normal conditions
  • Corrosivity
    • Extremely Corrosive
  • Evaporation Rate
    • Not applicable
  • Flammability
    • Not applicable
  • Ignition Temperature
    • Not applicable
  • Incompatible Materials
    • Contact with alkalies and some oxides cause strong violent exothermic reactions
    • Contact with metals will yield hydrogen gas, a fire and explosive reactive hazard
    • Glass and silicate-containing materials are attacked
    • HF contact with carbonates, sulfides and cyanides yield toxic gases such as carbon dioxide, hydrogen sulfide and hydrogen cyanide
    • HF contact with glass, concrete and other silicon bearing materials will yield silicon tetrafluoride gas
    • On dilution or dissolving in water, considerable heating always occurs
    • Pressure buildup from this process has been known to rupture glass containers
    • When diluting, add acids to water, never the other way around
  • Oxidizing
    • The substance or mixture is not classified as oxidizing
  • Self Ignition
    • Not applicable
  • Thermal Decomposition
    • Fire or intense heat may cause violent rupture of packages

International Transportation

  • Chemical Class
    • 8
  • Packing Group
    • I
  • Sub Class 1
    • 6.1
  • UN Number
    • 1052
  • Application : Blowing Agents|Petrochemical|Plastics|Refrigerants|Solvents
  • Synonyms : AHF|Anhydrous HF|HF|HF Acid
  • CAS Number : Hydrogen Fluoride - 7664-39-3
  • EC Number : 231-634-8
  • Product Type : Substance Degrees Celsius
  • Grade : Anhydrous
  • Color : Colorless
  • Formula : HF
  • Solubility in Water : Completely miscible
  • Melting Point/Range : -83 °C
  • Odor : Intolerable Pungent
  • Flashpoint : Not applicable
  • Density : 1,000 g/cm3 at 20 °C
  • pH : Acidic
  • Physical Form : Liquid
  • Partition Coefficient : No data available
  • Chemical Composition : Hydrogen Fluoride
  • Boiling Point/Range : 19.5 °C at 1.013 hPa
  • Vapor Pressure : 1.028 hPa at 20 °C hectopascal
  • Self Ignition : Not applicable
  • Oxidizing : The substance or mixture is not classified as oxidizing
  • Chemical Stability : Fire or intense heat may cause violent rupture of packages|Stable under normal conditions
  • Incompatible Materials : Contact with alkalies and some oxides cause strong violent exothermic reactions|Contact with metals will yield hydrogen gas, a fire and explosive reactive hazard|Glass and silicate-containing materials are attacked|HF contact with carbonates, sulfides and cyanides yield toxic gases such as carbon dioxide, hydrogen sulfide and hydrogen cyanide|HF contact with glass, concrete and other silicon bearing materials will yield silicon tetrafluoride gas|On dilution or dissolving in water, considerable heating always occurs|Pressure buildup from this process has been known to rupture glass containers|When diluting, add acids to water, never the other way around
  • Flammability : Not applicable
  • Evaporation Rate : Not applicable
  • Ignition Temperature : Not applicable
  • Thermal Decomposition : Fire or intense heat may cause violent rupture of packages
  • Corrosivity : Extremely Corrosive
  • Chemical Class : 8
  • Packing Group : I
  • UN Number : 1052
  • Sub Class 1 : 6.1
  • Concentration : 100% Hydrogen Fluoride
  • Performance Function : Fluorinated Carbon Compounds
Technical Note
Name
Description
File Size
Date
Size
Typical Alkaline Material (Bases)
application/pdf 89.25 KB
3/21/2024
89.25 KB
Brochure
Name
Description
File Size
Date
Size
Supporting remediation efforts
application/pdf 3.3 MB
6/18/2024
3.3 MB
In Person & Online Seminars
application/pdf 1.63 MB
6/18/2024
1.63 MB
#1 Choice for HF Acid
application/pdf 1.65 MB
6/18/2024
1.65 MB
Anhydrous and aqueous customers
application/pdf 3.46 MB
6/18/2024
3.46 MB
Emergency preparedness
application/pdf 2.77 MB
6/18/2024
2.77 MB
Safe production and transportation of HF
application/pdf 1.56 MB
6/18/2024
1.56 MB
Honeywell expertise can reduce risk and downtime
application/pdf 2.49 MB
6/18/2024
2.49 MB
Training Guide
application/pdf 4.38 MB
6/17/2024
4.38 MB
Training Guide
application/pdf 707.05 KB
6/6/2024
707.05 KB
Our Driver Teams Use Advanced Fleet Technology
application/pdf 762.71 KB
6/4/2024
762.71 KB
Data Sheet
Name
Description
File Size
Date
Size
NA MSDS
application/pdf 486.01 KB
4/2/2024
486.01 KB
Technical Data Sheet
application/pdf 72.4 KB
3/21/2024
72.4 KB
Technical Data Sheet
application/pdf 75.13 KB
3/21/2024
75.13 KB
Name
Description
File Size
Date
Size
Typical Alkaline Material (Bases)
application/pdf 89.25 KB
3/21/2024
89.25 KB
Supporting remediation efforts
application/pdf 3.3 MB
6/18/2024
3.3 MB
In Person & Online Seminars
application/pdf 1.63 MB
6/18/2024
1.63 MB
#1 Choice for HF Acid
application/pdf 1.65 MB
6/18/2024
1.65 MB
Anhydrous and aqueous customers
application/pdf 3.46 MB
6/18/2024
3.46 MB
Emergency preparedness
application/pdf 2.77 MB
6/18/2024
2.77 MB
Safe production and transportation of HF
application/pdf 1.56 MB
6/18/2024
1.56 MB
Honeywell expertise can reduce risk and downtime
application/pdf 2.49 MB
6/18/2024
2.49 MB
Training Guide
application/pdf 4.38 MB
6/17/2024
4.38 MB
Training Guide
application/pdf 707.05 KB
6/6/2024
707.05 KB
Our Driver Teams Use Advanced Fleet Technology
application/pdf 762.71 KB
6/4/2024
762.71 KB
NA MSDS
application/pdf 486.01 KB
4/2/2024
486.01 KB
Technical Data Sheet
application/pdf 72.4 KB
3/21/2024
72.4 KB
Technical Data Sheet
application/pdf 75.13 KB
3/21/2024
75.13 KB
Name
Description
File Size
Date
Size
Typical Alkaline Material (Bases)
89.25 KB
3/21/2024
Supporting remediation efforts
3.3 MB
6/18/2024
In Person & Online Seminars
1.63 MB
6/18/2024
#1 Choice for HF Acid
1.65 MB
6/18/2024
Anhydrous and aqueous customers
3.46 MB
6/18/2024
Emergency preparedness
2.77 MB
6/18/2024
Safe production and transportation of HF
1.56 MB
6/18/2024
Honeywell expertise can reduce risk and downtime
2.49 MB
6/18/2024
Training Guide
4.38 MB
6/17/2024
Training Guide
707.05 KB
6/6/2024
Our Driver Teams Use Advanced Fleet Technology
762.71 KB
6/4/2024
Technical Data Sheet
72.4 KB
3/21/2024
Technical Data Sheet
75.13 KB
3/21/2024